Verb
To employ or place so as to make alliteration.
To compose alliteratively; also, to constitute alliteration.
Source: Webster's dictionaryNote also the pervasive pattern of alliteration, where the first and/or second stress alliterate with the third, but not with the fourth. Source: Internet
Vowels alliterate with any other vowel, as with æþelingas main and ellen main. Source: Internet