Word info

antibonding

Adjective

Meaning

antibonding (not comparable)

(chemistry, physics) Describing an atomic or molecular orbital whose energy increases as its constituent atoms are brought closer together - thus generating a repulsive force that hinders bonding.

Source: en.wiktionary.org

Examples

Bonding can be described with three bonding electron pairs and two antibonding electrons, whose spins are aligned, such that the molecule has nonzero total angular momentum. Source: Internet

Another way of looking at it is that there are two bonding electrons and two antibonding electrons; therefore, the bond order is 0 and no bond exists (the molecule has one bound state supported by the Van der Waals potential). Source: Internet

A δ bonding orbital has two nodal planes containing the internuclear axis, and a δ* antibonding orbital also has a third nodal plane between the nuclei. Source: Internet

A σ* orbital, sigma antibonding orbital, also maintains the same phase when rotated about the internuclear axis. Source: Internet

H 2 Electron wavefunctions for the 1s orbital of a lone hydrogen atom (left and right) and the corresponding bonding (bottom) and antibonding (top) molecular orbitals of the H 2 molecule. Source: Internet

A π* orbital, pi antibonding orbital, will also produce a phase change when rotated about the internuclear axis. Source: Internet

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