of all
Adverb
Meaning
Used as an intensifier with superlative forms of adjectives.
Best of all was the bicycle I got. First of all, I'd like to thank my agent. He was the greatest playwright of all.
Used as an intensifier with nouns to denote being ultimate.
Source: en.wiktionary.orgExamples
Care most of all for your soul, brother, it is your only treasure. Everything else you own, doesn't really belong to you.
Ignorance, the root and stem of all evil.
Experience is the teacher of all things.
Thinking well is wise; planning well, wiser; but doing well is the wisest and best of all.
Medicine is the noblest of all arts.
Money is the root of all evil.